- (2002) TV commercial for McDonalds.
- (2003) Print ads for Close-Up toothpaste "Serena Williams Limited Edition" Red Gel.
- TV commercial for Double-Mint Gum, with sister Venus
- (2000) Print ad for the Wilson Hyper Hammer 6.3 Hyper-Carbon racket.
- (2003) Print ads for Doublemint Chewing Gum from Wrigley.
- (2002) Print ad for Avon.
- (2005 - 2006) Print ads for the America's Milk Processors'"got milk?" milk mustache campaign.
- (2007) Print ads for Vicks Sinus NyQuil & DayQuil products and trip to Wimbledon contest promotion.
- (2009) Appeared in Common's music video for Melnik (2018)".
- (2009) TV commercials for "Oreo" cookies, with sister Venus Williams, in a competition with pro football's Manning brothers.
- (2009 - 2011) Print ads for Tampax Pearl tampons from Playtex.
- (2008) Print ads for Wilson's [K] Blade racquet with sister Venus Williams.
- (2010) Print ads for Gatorade sports drinks congratulating her as the "Queen of Aces".
- (2011) Appeared in Enrique Iglesias's music video for Enrique Iglesias Feat. Pitbull & The WAV.s: I Like How It Feels (2011).
- (2011) Print ads for O.P.I. nail enamels and polishes.
- (2017) TV commercial "Battle of the Paddle", with Stephen Curry, for JPMorgan Chase Bank's QuickPay mobile application.
- (2017) TV commercial for Mission Max cooling towel with Drew Brees and Dwyane Wade
- (2018) TV commercial for JPMorgan Chase Bank.
- (2020) TV commercial for Bolt 24 Hour energy drink.
- (2020) TV commercial for Secret Deodorants for women.
- (2020) TV commercial for Ubrelvy Tablets migraine medication from Allergan USA.
- (2020) TV commercial for Nintendo switch.
- (August 2021) TV commercial, with Serena Williams, John McEnroe, and Gal Gadot (as Wonder Woman) for the new DirectTV Stream streaming service from DirectTV satellite.
- (February 2022) TV commercial: Michelob Ultra with Peyton Manning, Alex Morgan, Brooks Koeepka, Nneka Ogwumkke, Jimmy Butler, and Steve Buscemi
- (2022) TV commercial: Tonal Equipment
- (February 2023) TV commercial: Remy Martin Cognac
- (February 2023) TV commercial: Michelob Ultra with Brian Cox, Alex Morgan, Tony Romo, Canelo Alvarez, Jimmy Butler, Nneka Oswumike, and Michael O'Keefe
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